Copolymerization of cyclohexene oxide with CO2 catalyzed by tridentate N-heterocyclic carbene titanium(IV) complexes.
نویسندگان
چکیده
A new class of complexes based on titanium(IV) bearing a bisanionic mer-tridentate N-heterocyclic carbene ligand were investigated for the copolymerization of cyclohexene oxide with CO2. Upon addition of [PPN]X' salts, all complexes were found to be active and highly selective toward the formation of poly(cyclohexene oxide-alt-carbon dioxide).
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ورودعنوان ژورنال:
- Dalton transactions
دوره 43 11 شماره
صفحات -
تاریخ انتشار 2014